Equipment List:
Spectroscopes
Hydrogen Source tubes
Power supplies for the tubes
Mercury calibration sources
Tensor lamps
Purpose:
To measure the wavelengths of the visible spectrum
of hydrogen for as many orders as possible and compare to the accepted
values.
Introduction:
Elements emit light when excited. When only one
element is emitting the light, the wavelengths of emitted light are not
continously distributed but are only emitted at certain discrete
wavelengths.
Explaining why this is so is a great triumph of early quantum
mechanics.
Procedure:
Set up your equipment. Check the alignment; your instructor will
hopefully
be of help. Start out by using the box-like mercury source that puts
out
a strong green line. You can check the calibration of your spectroscope
(and your ability to use it accurately) by confirming that the
wavelength
of the green line is 546.074 nm. The darker the room and surroundings,
the better your chance to clearly see the spectrum of hydrogen for more
than one order. The visible wavelengths have the colors violet,
blue-violet,
blue-green, and red. You should be easily able to see at least three of
these. The red wavelength is particularly easy to observe; maybe you
should start
with that color and see if everything is working properly.
Data:
Record the angles for all visible lines. For each order, you should
record the data for each individual wavelength at BOTH sides of the
center
maximum and then average those two values (what does this accomplish?).
Ideally, you would have a total of sixteen angles; one angle for each
of
the four visible wavelengths of the Balmer series. Get four angles for
the first order left side, four more angles for the second order left
side,
four angles for the first order right side of the central maximum, and
four angles for the second order right side. That's four different
angles
for each of the four different wavelengths.
Analysis:
Compare your measured values of the four wavelengths to the accepted
values as calculated from the Rydberg equation for the Balmer series.